No, this doesn't quite work. Masculine and feminine are scaleable adjectives, but man and woman are binary nouns.
No matter how 'masculine' a combat-booted bulldyke presents, we recognise her as a woman and we judge her as a woman. A lot of people might judge her as failed women, or unnatural women, but they still recognise that she's a women. Even if she's a hundred times more masculine than the effeminate man standing next to her, we still very clearly see a masculine woman and a feminine man, and we judge them accordingly.
You can be seen as any level of 'masculine' or 'feminine', regardless of your sex, but you either are, or you are not seen as a man or a woman. If a XX female presents so perfectly as male that the world around her doesn't know she's trans, and just sees her as a man, and treats her as a man, and behaves around her as if she's a man, then how can we really call her sociologically feminine or female, when she's liberated of all the social responsibilities and expectations of womanhood but burdened with all the social responsibilities and expectations of manhood? She will always be female, but regardless of her chromosomes or vagina, she's become a man, even if the English language lacks universally agreed-on words to recognise that.